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arp percentages arent additive like that. i dont know how to calculate it though, and blizzard has only released their way of calculating it for players lvl 60+. someone would have to get the gear and run #s against players of different armor lvls to figure it out
iirc though, mace spec/grim toll/etc are most effective when they will bring you exactly to the armor pen cap (100%). armor pen usually isnt good for 80 classes until you can get 35-40%